Growth of gallium nitride (GaN) on strain relaxed nanoporous GaN template by
metal-organic chemical vapor deposition has produced GaN layer with
60% reduction in threading dislocation density (TDD). The porous GaN was
annealed at 850 °C for 3 min in a mixed of
nitrogen and ammonia ambient, which annihilated most TDs within the porous
region via air-gap formation coupled with surface edge step pinning of
dislocations. Enhancement of optical quality was indicated by doubled Raman
intensity of E2 phonon peak of annealed porous as compared
to as-fabricated porous GaN. Besides, a redshift of 0.7 cm-1 in E2 phonon
peak of porous GaN with respect to as-grown GaN corresponds
to a relaxation of compressive stress by 0.17±0.05 GPa. Further
overgrowth of GaN on annealed porous GaN template gives
high quality GaN with reduction in TDD.
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