This study demonstrates improvement of crystal quality of
GaN film by growing it on a micro-faceted GaN template fabricated by in situ
etching with an HCl/N2 etching gas mixture at 1050 °C in hydride
vapor phase epitaxy (HVPE) reactor. Cathodoluminescence images of the
cross-sectional structure showed that there were six sublays in the GaN film
grown with in situ etching for five times. Etch pit density (EPD) and
high-resolution X-ray diffraction (HR-XRD) measurements showed that the crystal
quality of GaN thick film grown on micro-faceted GaN template was better than
that of the as-grown GaN. A large number of columnar structures were formed on
the micro-faceted GaN template at the initial stage of regrowth process, the
coalescence of which played an important role in the reduction of threading
dislocation density during the GaN growth. A model has been developed to
explain the mechanism of forming process of the columnar structures.
Source: Applied Surface Science
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